Strontium Isotopic Variations of Neoproterozoic Seawater: Implications for Crustal Evolution

We report high precision Sr isotopic data on carbonates from the Neoproterozoic Shaler Group, Victoria Island, Northwest Territories, Canada. Lithostratigraphic correlations with the relatively well-dated Mackenzie Mountains Supergroup constrain Shaler deposition to approximately 770-880 Ma, a range corroborated by 723 +/- 3 Ma lavas that disconformably overlie Shaler carbonates and by Late Riphean microfossils within the section. Samples with low Rb-87/Sr-86 ratios (< 0.01) were selected for Sr isotopic analysis. delta-O-18, Mn, Ca, Mg, and Sr data were used to recognize altered samples. The altered samples are characterized by high Mn/Sr (greater-than-or-equal-to 2) and variable delta-O-18; most are dolomites. The data indicate that between ca. 790-850 Ma the Sr-87/Sr-86 ratio of seawater varued between 0.70676 and 0.70561. The samples show smooth and systematic variation, with the lowest Sr-87/Sr-86 value of 0.70561 at ca. 830 Ma. The low Sr-87/Sr-86 ratio of carbonates from the lower parts of our section is similar to a value reported for one sample from the Adrar of Mauritania (almost-equal-to 900 Ma), West African Craton. Isotopic ratios from the upper part of the Shaler section are identical to values from the lower part of the Neoproterozoic Akademikerbreen Group, Spitsbergen. Although a paucity of absolute age determinations hinders attempts at the precise correlation of Neoproterozoic successions, it is possible to draw a broad outline of the Sr isotopic composition of seawater for this period. Indeed, the Sr isotope data themselves provide a stratigraphic tool of considerable potential. Data from this study and the literature are used to construct a curve of the Sr-87/Sr-86 ratio of Neoproterozoic seawater. The new data reported in this study substantially improve the isotopic record of Sr in seawater for the period 790-850 Ma. The Sr isotope composition of seawater reflects primarily the balance between continental Sr input through river input and mantle input via hydrothermal circulation of seawater through mid-ocean ridges. Coupling of Nd and Sr isotopic systems allows us to model changes in seafloor spreading rates (or hydrothermal flux) and continental erosion. The Sr hydrothermal flux and the erosion rate (relative to present-day value) are modeled for the period 500-900 Ma. The results indicate that the hydrothermal flux reached a maximum value at ca. 830 Ma. In contrast, a large peak in erosion rate is indicated at ca. 570 Ma. The peaks in hydrothermal flux and erosion rate are most likely related to developments in the Pan-African and related orogenic events, whose initial development is characterized by production of juvenile crust during supercontinental break up and rifting. The time ca. 570 Ma is characterized by continent-continent collision and production of recycled crust. Sr isotope data from Proterozoic carbonates offer a valuable resource for understanding large-scale crust dynamics.Earth and Planetary SciencesOrganismic and Evolutionary Biolog

Hydroclimate variability from western Iberia (Portugal) during the Holocene: insights from a composite stalagmite isotope record

© The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Thatcher, D. L., Wanamaker, A. D., Denniston, R. F., Asmerom, Y., Polyak, V. J., Fullick, D., Ummenhofer, C. C., Gillikin, D. P., & Haws, J. A. Hydroclimate variability from western Iberia (Portugal) during the Holocene: insights from a composite stalagmite isotope record. Holocene, (2020): 095968362090864, doi:10.1177/0959683620908648.Iberia is predicted under future warming scenarios to be increasingly impacted by drought. While it is known that this region has experienced multiple intervals of enhanced aridity over the Holocene, additional hydroclimate-sensitive records from Iberia are necessary to place current and future drying into a broader perspective. Toward that end, we present a multi-proxy composite record from six well-dated and overlapping speleothems from Buraca Gloriosa (BG) cave, located in western Portugal. The coherence between the six stalagmites in this composite stalagmite record illustrates that climate (not in-cave processes) impacts speleothem isotopic values. This record provides the first high-resolution, precisely dated, terrestrial record of Holocene hydroclimate from west-central Iberia. The BG record reveals that aridity in western Portugal increased secularly from 9.0 ka BP to present, as evidenced by rising values of both carbon (δ13C) and oxygen (δ18O) stable isotope values. This trend tracks the decrease in Northern Hemisphere summer insolation and parallels Iberian margin sea surface temperatures (SST). The increased aridity over the Holocene is consistent with changes in Hadley Circulation and a southward migration of the Intertropical Convergence Zone (ITCZ). Centennial-scale shifts in hydroclimate are coincident with changes in total solar irradiance (TSI) after 4 ka BP. Several major drying events are evident, the most prominent of which was centered around 4.2 ka BP, a feature also noted in other Iberian climate records and coinciding with well-documented regional cultural shifts. Substantially, wetter conditions occurred from 0.8 ka BP to 0.15 ka BP, including much of the ‘Little Ice Age’. This was followed by increasing aridity toward present day. This composite stalagmite proxy record complements oceanic records from coastal Iberia, lacustrine records from inland Iberia, and speleothem records from both northern and southern Spain and depicts the spatial and temporal variability in hydroclimate in Iberia.The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was supported, in part, by the US National Science Foundation (Grants: #1804528 to ADW; #1804635 to RD; #1804132 to CCU; #1806025 to YA and VP; #1805163 to DPG; BCS-0455145, BCS-0612923, and BCS-1118155 to JAH)

Decoupling of monsoon activity across the northern and southern Indo-Pacific during the Late Glacial

© The Author(s), 2017. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Quaternary Science Reviews 176 (2017): 101-105, doi:10.1016/j.quascirev.2017.09.014.Recent studies of stalagmites from the Southern Hemisphere tropics of Indonesia revealed two shifts in monsoon activity not apparent in records from the Northern Hemisphere sectors of the Austral-Asian monsoon system: an interval of enhanced rainfall at ~19 ka, immediately prior to Heinrich Stadial 1, and a sharp increase in precipitation at ~9 ka. Determining whether these events are site-specific or regional is important for understanding the full range of sensitivities of the Austral-Asian monsoon. We present a discontinuous 40 kyr carbon isotope record of stalagmites from two caves in the Kimberley region of the north-central Australian tropics. Heinrich stadials are represented by pronounced negative carbon isotopic anomalies, indicative of enhanced rainfall associated with a southward shift of the intertropical convergence zone and consistent with hydroclimatic changes observed across Asia and the Indo- Pacific. Between 20-8 ka, however, the Kimberley stalagmites, like the Indonesian record, reveal decoupling of monsoon behavior from Southeast Asia, including the early deglacial wet period (which we term the Late Glacial Pluvial) and the abrupt strengthening of early Holocene monsoon rainfall.Funded by grants from the U.S. National Science Foundation Paleo Perspectives on Climate Change program (AGS-1103413 and AGS-1502917 to RFD) and AGS-1602455 (to CCU and RFD), the Center for Global and Regional Environmental Research, and Cornell College (to RFD). CCU acknowledges support from The Investment in Science Fund given primarily by WHOI Trustee and Corporation Members. Support also received from the Kimberley Foundation Australia

Exceptionally stable pre-industrial sea level inferred from the western Mediterranean Sea

An accurate record of pre-industrial (pre-1900 CE) sea level is necessary to place modern global mean sea-level rise in context with respect to natural variability. We present new results from precisely dated phreatic overgrowths on speleothems (POS) that preserve a detailed history of Late Holocene sea level. These data indicate that the largest sea-level jump occurred between 0.12 and 0.31 m (95% confidence) from 3.26 to 2.84 ka BP (2σ). Our results show that relative sea level stayed within 0.08 m (95% confidence) of pre-industrial levels from 2.84 ka BP to 1900 CE. This sea-level history is consistent with models of glacial isostatic adjustment that adopt a relatively weak upper mantle viscosity of ~1020 Pa s. Models indicate virtual certainty (> 0.999 probability) that rates of sea-level rise over the past 4 ka (including the 400-year jump) have not approached the global average since 1900 CE; therefore, recent sea-level rise cannot be explained by natural variability

Sensitivity of northwest Australian tropical cyclone activity to ITCZ migration since 500 CE

Tropical cyclones (TCs) regularly form in association with the intertropical convergence zone (ITCZ), and thus, its positioning has implications for global TC activity. While the poleward extent of the ITCZ has varied markedly over past centuries, the sensitivity with which TCs responded remains poorly understood from the proxy record, particularly in the Southern Hemisphere. Here, we present a high-resolution, composite stalagmite record of ITCZ migrations over tropical Australia for the past 1500 years. When integrated with a TC reconstruction from the Australian subtropics, this time series, along with downscaled climate model simulations, provides an unprecedented examination of the dependence of subtropical TC activity on meridional shifts in the ITCZ. TCs tracked the ITCZ at multidecadal to centennial scales, with a more southward position enhancing TC-derived rainfall in the subtropics. TCs may play an increasingly important role in Western Australia’s moisture budgets as subtropical aridity increases due to anthropogenic warming

Abandonment of Unaweep Canyon (1.4–0.8 Ma), western Colorado: Effects of stream capture and anomalously rapid Pleistocene river incision

Cosmogenic-burial and U-series dating, identification of fluvial terraces and lacustrine deposits, and river-profile reconstructions show that capture of the Gunnison River by the Colorado River and abandonment of Unaweep Canyon occurred between 1.4-0.8 Ma. This event led to a rapid pulse of incision unlike any documented in the Rocky Mountains. Following abandonment of Unaweep Canyon by the ancestral Gunnison River, a wave of incision propagated upvalley rapidly through Mancos Shale at rates of ~90-440 km/Ma. The Gunnison River removed 400-500 km3 of erodible Mancos Shale and incised up to 360 m deep in 0.17-0.76 My (incision rates of ~470-2250 m/Ma). Prior to canyon abandonment, long-term (~11-1 Ma) Gunnison River incision averaged ~100 m/Ma. The wave of incision also caused the subsequent capture of the Bostwick-Shinn Park River by the ancestral Uncompahgre River ca. 0.87-0.64 Ma, at a location ~70 km upvalley from Unaweep Canyon. This event led to similarly rapid (up to ~500 m/Ma) but localized river incision. As regional river incision progressed, the juxtaposition of resistant Precambrian bedrock and erodible Mancos Shale within watersheds favored the development of significant relief between adjacent stream segments, which led to stream piracy. The response of rivers to the abandonment of Unaweep Canyon illustrates how the mode and tempo of long-term fluvial incision are punctuated by short-term geomorphic events such as stream piracy. These short-term events can trigger significant landscape changes, but the effects are more localized relative to regional climatically- or tectonically-driven events. Powered byThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the Geological Society of America and can be found at: http://geosphere.gsapubs.org/.Keywords: Stream piracy, Gunnison River, Knickpoint, Fluvial incision, Unaweep Canyo

Aerosol forcing of the position of the intertropical convergence zone since AD1550

The position of the intertropical convergence zone is an important control on the distribution of low-latitude precipitation. Its position is largely controlled by hemisphere temperature contrasts1, 2. The release of aerosols by human activities may have resulted in a southward shift of the intertropical convergence zone since the early 1900s (refs 1, 3, 4, 5, 6) by muting the warming of the Northern Hemisphere relative to the Southern Hemisphere over this interval1, 7, 8, but this proposed shift remains equivocal. Here we reconstruct monthly rainfall over Belize for the past 456 years from variations in the carbon isotope composition of a well-dated, monthly resolved speleothem. We identify an unprecedented drying trend since ad 1850 that indicates a southward displacement of the intertropical convergence zone. This drying coincides with increasing aerosol emissions in the Northern Hemisphere and also marks a breakdown in the relationship between Northern Hemisphere temperatures and the position of the intertropical convergence zone observed earlier in the record. We also identify nine short-lived drying events since ad 1550 each following a large volcanic eruption in the Northern Hemisphere. We conclude that anthropogenic aerosol emissions have led to a reduction of rainfall in the northern tropics during the twentieth century, and suggest that geographic changes in aerosol emissions should be considered when assessing potential future rainfall shifts in the tropics

ICDP workshop on the Lake Tanganyika Scientific Drilling Project: a late Miocene–present record of climate, rifting, and ecosystem evolution from the world's oldest tropical lake

The Neogene and Quaternary are characterized by enormous changes in global climate and environments, including global cooling and the establishment of northern high-latitude glaciers. These changes reshaped global ecosystems, including the emergence of tropical dry forests and savannahs that are found in Africa today, which in turn may have influenced the evolution of humans and their ancestors. However, despite decades of research we lack long, continuous, well-resolved records of tropical climate, ecosystem changes, and surface processes necessary to understand their interactions and influences on evolutionary processes. Lake Tanganyika, Africa, contains the most continuous, long continental climate record from the mid-Miocene (∼10 Ma) to the present anywhere in the tropics and has long been recognized as a top-priority site for scientific drilling. The lake is surrounded by the Miombo woodlands, part of the largest dry tropical biome on Earth. Lake Tanganyika also harbors incredibly diverse endemic biota and an entirely unexplored deep microbial biosphere, and it provides textbook examples of rift segmentation, fault behavior, and associated surface processes. To evaluate the interdisciplinary scientific opportunities that an ICDP drilling program at Lake Tanganyika could offer, more than 70 scientists representing 12 countries and a variety of scientific disciplines met in Dar es Salaam, Tanzania, in June 2019. The team developed key research objectives in basin evolution, source-to-sink sedimentology, organismal evolution, geomicrobiology, paleoclimatology, paleolimnology, terrestrial paleoecology, paleoanthropology, and geochronology to be addressed through scientific drilling on Lake Tanganyika. They also identified drilling targets and strategies, logistical challenges, and education and capacity building programs to be carried out through the project. Participants concluded that a drilling program at Lake Tanganyika would produce the first continuous Miocene–present record from the tropics, transforming our understanding of global environmental change, the environmental context of human origins in Africa, and providing a detailed window into the dynamics, tempo and mode of biological diversification and adaptive radiations.© Author(s) 2020. This open access article is distributed under the Creative Commons Attribution 4.0 License